I know there are prestige classes for casters, but due to the Warlock's Invocation mechanics, I'm not sure which ones it can qualify for, or at least which ones would be beneficial for it. What are some good prestige classes for Warlocks?
Warlock Prestige Class Eligibility
Basically, there are three rules:
Complete Arcane explains each of these on page 71. Page 18 describes how a warlock benefits from a spellcasting prestige class.
What Prestige Classes Does a Warlock Actually Qualify For?
List questions are not on topic here, but the short answer is, “not many.” Wizards made a few in Complete Arcane, but both before and after Complete Arcane, being able to cast spells of a given level have been by-far the most common sort of requirement for a spellcasting prestige class. Complete Arcane does, at least, list each of its own prestige classes by which base classes each is best for, so you can search Table 2‐1 on page 18 for that.
From other books, Complete Mage and Dragon Magic both add new invocations, and I know Complete Mage does have a few classes that warlocks can qualify for. There are other places scattered around that have prestige classes they can take, but there are not many.
I do recommend houseruling the warlock qualifications to allow them to take prestige classes that require casting spells of a given level.
There are simply too many prestige classes that are too fitting and appropriate to deny them to warlocks. Just allow them to qualify for a prestige class if a wizard of their (effective) level could cast spells of the required level. Some class benefits (bonus spell slots, metamagic effects, extra spells known) are meaningless for them, but still, a discerning player should be able to find useful things. The warlock is not a high-powered class; it’s a good idea to offer them easy upgrades like this.
For those particularly enamored of the RAW...
The notorious Precocious Apprentice feat from Complete Arcane can... arguably be taken by warlocks. If that is the case, they’d get a 2nd-level spell slot for doing so, and can then take prestige classes that require 2nd-level spells. Said prestige classes can then progress their warlock invocations as normal. This is not recommended; just houserule warlock prestige class entry and be done with it.
Notable Warlock Prestige Classes
Just a couple of prestige classes that deserve special mention.
Of course, the best warlock prestige class is the hellfire warlock from Fiendish Codex II: Tyrants of the Nine Hells. This class is three-levels long, adds +2d6 Hellfire Blast damage each level, and advances invocations on each level. Hellfire Blasts also do Constitution damage to yourself, and the class specifically states that you cannot use Hellfire Blast if you are immune to Constitution damage. A one-level dip in binder (Tome of Magic) for Naberius, the Grinning Hound is the most common way to heal that up quickly and easily. A one-level dip in incarnate for strongheart vest might work, depending on how your DM reads the immunity rule (strongheart vest basically gives you DR for ability damage, but it does not give immunity; YMMV).
Hellfire warlock is so good that a lot of warlock optimizers abuse legacy champion (Weapons of Legacy), which has the class feature of advancing another class’s features (like +1 spellcasting level, but for any sort of level and advancing anything). By RAW, this allows you to have more than three effective hellfire warlock levels, and therefore more than the +6d6 damage that it usually grants. A lot of DMs take a pretty dim view of that rule, however.
This is not a warlock prestige class, and nothing about warlock makes it easier to enter (it only requires a feat and some skills). It does not advance invocations. What it does do, however, is give you a “floating feat” – a Chameleon 2’s Bonus Feat can be changed every day.
This is relevant to warlocks because at level 12, they gain Imbue Item, the ability to craft magical items without knowing the requisite spell. They still need the feat, however: Chameleon 2 means that they can swap in whatever Item Creation feat they like for these purposes, and on days when they’re not crafting, they can just swap it to Extra Invocation. Along similar lines, they can swap it to Extra Invocation (the dead walk) to build an undead army on down days, then swap it to something combat-oriented when they go into battle – without the dead walk, they won’t be able to animate any more minions, but they will keep the minions they’ve already made.
If he's a good Warlock he could take enlightened spirit from Complete mage.
The Enlightened spirit gives you bonus dice to your Eldritch Blast and lets you make it spirit blast to do bonus damage to undead, or you can make it holy, you can also fly with it with an invoaction you get for free from it
There's Eldritch theurge if you want to mix arcane and invocations. As well as being able to put spells on your eldritch blasts, putting invocations onto spells, and gaining DR and fiendish resilience.
there's the Eldritch disciple if you'd rather go down a divine path, giving you the choice of 3 different divine patron abilities given in the class description, and getting timeless body at its tenth level. The levels also stack with any turning/energy channeling you have from divine classes.
These are just the specifics from complete mage alone. Though they are specifically for Warlocks