And if not, what would you recommend using? I've always thought it would make for some interesting gaming.
There hasn't been a formally released Culture game, no. However:
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An unofficial Champions/Hero System adaptation has been done.
Its original website is missing, but it is archived at http://web.archive.org/web/*/http://www.sden.org/jdr/spaceopera/download/GB/IainBanks.pdf
as of this writing, the link works.