It appears to me, that you can only use the attack power once per round.
The effect says 'each time... you can'. Meaning it's an option available to you. But the attack power itself means that it can only happen once per round.
I would suggest eratta on this, as it seems poorly worded. :)
However it might be correct because the effect is the effect that gives you a new power while the stance exists. It doesn't mean that you can always use that power since the power is written in a way which says you can't.
i.e. the power itself, is a specific rule, which override the general rule of 'each time.. etc.'
The chain of actions goes like this:
Evoke daily:
- Adjacent enemy 1 attacks. Attempt to use Deulist's prowess. Done.
- Adjacent enemy 2 attacks. Attempt to use Deulist's prowess.. power usage is blocked by fact that it is only an immediate interrupt and can only be done once per round. However the stance is still active.