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There is one part of the question that isn't clear and is not addressed by SevenSidedDie: Can you choose to not activate an immediate reaction on the first occurrence of a trigger? Immediate Actions are Choices Since Immediate Actions are a choice, you can always choose to not activate a power on a trigger. If you choose not to, then you cannot use that ...

Just once per round Each here is a once per round effect, unless you have a way to provide yourself with more than one immediate action in a round (I'm not aware of any right off hand). The each allows the trigger to be valid for the rest of the encounter. The problem is that the action is described as an immediate reaction. immediate actions are defined ...

Yes, it has to be used right away. Not because it's an immediate action, but because it comes from a power that has just triggered. You don't get to choose when triggered powers take effect, even if going through with them is optional – they apply when, and only when their trigger condition happens.