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The feat Cosmopolitan gives you access to two INT, WIS, or Charisma based skills as class skill, and the Keeper of the Veil regional trait gives you access to Bluff or Disguise as a class skill and also grants a +1 bonus to both of those skills.
Yes, a Synthesist can us the Skilled Evolution while fused. The synthesist gains access to evolutions, but no skill ranks or feats. This evolution does not give skill ranks or feats. It just happens to give a bonus to a skill, which is quite different.
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