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There isn't such thing as "complex character builds" in Dungeon World. So, probably it will not take long compared to other systems, in that it will be quick discounting the time it takes to learn how in the first place (which would be the same whatever system you were aiming at). But, there's not much point in doing it. Herolab doesn't really offer any ...
Yes, there is support for it (and all the other stuff in Ultimate Campaign) in Hero Lab. See this Wolf Lair forum post for what and where it is in the program. Hero Lab is expensive, but running Pathfinder without it is like stabbing yourself in the leg repeatedly. It makes NPC creation and management, and applying status and stuff in combat, so nice.
You could always use a spreadsheet or make a pack of note cards with names of the characters on them, recording notes as you go along through the pack in order.
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