This question asked whether a character can use a spell slot to cast a spell "learned" through a feat such as Magic Initiate or Fey Teleportation. The answer, in a nutshell, was: Yes, but only if the spell is on the spell list of the class providing the slot. So, for example, an elven wizard who learns misty step by taking the Fey Teleportation feat could use wizard spell slots to cast misty step, because misty step is on the wizard spell list.
A piece of the answer's rationale was the following guidance:
If you have spell slots, can you use them to cast the 1st-level spell you learn with the Magic Initiate feat?
Yes, but only if the class you pick for the feat is one of your classes.... In short, you must follow your character’s normal spellcasting rules, which determine whether you can expend spell slots on the 1st-level spell you learn from Magic Initiate.
Sage Advice Compendium v2.2 p. 8 (emphasis mine).
Let's imagine a multiclassed Rogue 3 (Arcane Trickster)/Wizard 2. According to the spellcasting rules for multiclassed characters, see PHB p. 164-165, this character would have two 2nd-level spell slots but would not -- at least not through his class levels -- be able to learn any 2nd-level spells.
Now imagine that this character gains a level, becomes a Rogue 4/Wizard 2, and takes the Fey Teleportation feat. He "learns" misty step, which is on both the the wizard spell list and the Arcane Trickster spell list (because the latter is really the former). He still has no access to 2nd-level spells through his levels in either class.
Can this character use spell slots to cast misty step even though he couldn't otherwise cast, or even learn, any 2nd-level spells?