## There is no facing by default 

Facing is an optional rule in D&D 3.5. You can see this from Flanking being a variant rule, that is introduced as follows:

> The standard d20 combat rules intentionally ignore the direction a creature faces. The rules assume that creatures are constantly moving and shifting within their spaces, looking in all directions during a fight.

Because there is no facing, there is no effect of being immobilized by web on facing. Immobilized is also not a formal condition. 

It would be up to the DM to decide if you can or cannot change orientation if stuck in a web for other purposes.